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How can my Volcarona learn Giga Drain in Pokémon Y?

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Volcarona can't learn Giga Drain in Pokémon X and Y. Volcarona could only learn Giga Drain through the Move Tutor in Pokémon Black and White 2.

So the only way to get a Volcarona with Giga Drain in your game is if you get a Volcarona on Pokémon Black 2 or White 2 teach it Giga Drain and transfer it to Pokémon X or Y using Pokémon Bank, or if you miraculously get one through trade.

Source: http://bulbapedia.bulbagarden.net/wiki/Volcarona_(Pokémon)

Hope I helped :)

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Volcarona can only be obtained from Gen 5. Without the use of Pokebank, there is no way to obtain a Volcorona with Giga Drain in Pokemon X or Y

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Wrong. You can have a Larvesta with the Friend Safari. It will not have Giga Drain, though.