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For example, if Greninja was poisoned, can it cure its poisoning by using Toxic Spikes?
I'm wondering if Kecleon and Greninja can use this in replacement of Lum berries.

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No.

Similar to how if you soak a poison type Pokemon and poison it, it will still have the poisoned status if it switches back.

The source might explain it better.

Hope I helped!

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