As of Generation IX, Copperajah is the only Pokémon with access to G-Max Steelsurge to set up sharp steel, also learning Stealth Rock. Hisuian Samurott does not learn any moves that set entry hazards besides Ceaseless Edge. Kleavor learns both Stone Axe and Stealth Rock, which both set up pointed stones. Smeargle, of course, learns all moves that set up entry hazards besides G-Max Steelsurge.
Two Entry Hazard Moves
/nds spikes, stealth rock (38 results)
Bonsly, Carbink, Carkol, Clodsire, Coalossal, Crustle, Deoxys, Diancie, Dwebble, Ferroseed, Ferrothorn, Forretress, Garchomp, Gastrodon, Gligar, Glimmet, Glimmora, Gliscor, Groudon, Iron Thorns, Mew, Omanyte, Omastar, Orthworm, Pineco, Quagsire, Rolycoly, Sandshrew, Sandslash, Sandslash-Alola, Sandy Shocks, Skarmory, Smeargle, Sudowoodo, Ting-Lu, Whiscash, Wooper, Wooper-Paldea
/nds spikes, toxic spikes (40 results)
Accelgor, Cacnea, Cacturne, Clodsire, Cloyster, Forretress, Froakie, Frogadier, Garbodor, Gligar, Glimmet, Glimmora, Gliscor, Greninja, Meowscarada, Mew, Naganadel, Omanyte, Omastar, Overqwil, Pincurchin, Pineco, Quagsire, Qwilfish, Qwilfish-Hisui, Roselia, Roserade, Scolipede, Shellder, Shelmet, Smeargle, Spidops, Tarountula, Toedscool, Toedscruel, Trubbish, Venipede, Vespiquen, Whirlipede, Wooper-Paldea
/nds spikes, sticky web:
Smeargle, Spidops, Tarountula
/nds stealth rock, toxic spikes:
Clodsire, Forretress, Gligar, Glimmet, Glimmora, Gliscor, Mew, Nidoking, Nidoqueen, Nihilego, Omanyte, Omastar, Pineco, Quagsire, Runerigus, Smeargle, Wooper-Paldea
/nds stealth rock, sticky web:
Shuckle, Smeargle
/nds toxic spikes, sticky web:
Ariados, Smeargle, Spidops, Spinarak, Tarountula
Three Entry Hazard Moves
/nds spikes, stealth rock, toxic spikes:
Clodsire, Forretress, Gligar, Glimmet, Glimmora, Gliscor, Mew, Omanyte, Omastar, Pineco, Quagsire, Smeargle, Wooper-Paldea
/nds spikes, stealth rock, sticky web:
Smeargle
/nds spikes, toxic spikes, sticky web:
Smeargle, Spidops, Tarountula
/nds stealth rock, toxic spikes, sticky web:
Smeargle