PokéBase - Pokémon Q&A
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You can do it in one of two ways:

Either you get a Shadow Tag Gothorita from a Psychic type Friend Safari in X/Y


You use the DexNav on Route 102 once you have acquired the National Pokedex and chain Gothita until you find one with Shadow Tag.

Source: Experience.

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Thanks? Planning using Eviolite shadow tag gothita(I know gothorita is NFE aswell, but gothita is to damn cute to pass up ^_^)