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I want to breed a competitive Choice Scarfed Larvesta. The moves that I want on it are Zen Headbutt, Wild Charge, U-turn, and Flare Blitz. How do I get Flare Blitz on it?

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In order to get a Level 1 Larvesta with Flare Blitz, you need to breed a female Volcarona with Flare Blitz(gets it via Heart Scale)with another Pokemon that can learn Flare Blitz, but is male. This is a method that can bypass Levels in moves.

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But can you breed a female Volcarona with a male Volcarona, both knowing flare blitz, and get it to be on Larvesta?
Yeah, that's fine