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In most of its Pokedex entries, it says that Victreebel's acid can dissolve anything. Why won't it melt James into a pool of James and a Team Rocket "R"?

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Theoretically, yes, Team Rocket James would become Team Rocket Jelly.

However, Pokémon is predominantly a children's show, and having Victreebel swallow James and then spit out his steaming, dissolving corpse would be way out of bounds.

My kid-friendly theory:

James' Victreebel has a permanent dry throat.

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Wanna trade now?
I love the dry throat. nice touch.
We can trade :)
I'm so sorry, I went to a soccer game, and now my bro's playing on my DS. Can we trade Wednesday. That's when my Easter Break starts.