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So I just leveled up my Charmeleon at the daycare from lvl 5 to lvl 100. However he did not evolve to Charizard. How car I make him evolve to a Charizard?

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Unfortunately, once he reaches Lv 100, there is no way to evolve a Pokémon such as Charmeleon that evolves via level-up (Pokémon that evolve with Stones or trading can still be evolved). Your best bet is to breed Charmeleon to get a Charmander and start fresh.

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How do I breed him?
If it's a male you'll have to use a Ditto.