PokéBase - Pokémon Q&A
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-Give it a massage in Cyllage City.
-Use the Soothing Bag in Super Training.
-Give it a Colourful Shake, Rare Soda, Ultra Rare Soda, Perilous Soup, or EV Juices from the Juice Shoppe in Lumiose City.
-Use Friendship raising berries. (Grepa, Hondew, Kelpsy, Pomeg, Qualot or Tamato.)
-Level up in a battle.
-Battle against a Gym Leader, Elite Four member, or the Champion.
-Use a Vitamin. (HP Up, Protein, Iron, Calcium, Zinc, Carbos, PP Up, PP Max, or a Rare Candy.)
-Walking 128 steps (sometimes).
-Use a Battle Item (only works if it has less than 200 happiness)

Doing these things will lower happiness:
-Letting it faint.
-Using Energy Powder, Heal Powder, Energy Root, or a Revival Herb.


Hope I helped!

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adding on as a reminder to OP that affection is different from happiness. The things stated in this answer are for happiness, which turn eevee into Espeon or Umbreon. If you want a Sylveon, you need high affection, which is gained in Pokémon Amie, as well as a fairy move.
you did cheers
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Pokémon sun and moon- have malasadas with it, use soothe bell, pet and give beans, or what I like to use, isle avue in poke pelago!

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