PokéBase - Pokémon Q&A
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Do you get Luvdisc in fishing or by surfing in moon in order to retrieve some heart scales?

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Route 9: Encountered by fishing.
Melemele Sea: Encountered by fishing.
Luvdisc
Source, with full encounter rates.

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Dang I got ninja'd.
Is there special rod for it?
Nope, there's only one fishing rod in Sun/Moon.
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You can find them by fishing at Route 9 or Melemele Sea.
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By the way, if you want to teach flamethrower to your Charizard, then it's probably easier to use the TM than it is to obtain and use a heart scale.

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