PokéBase - Pokémon Q&A
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I've got far too much time on my hands and a bunch of Pokemon games; aside from event Pokemon, what can I not obtain? I have Ruby, Sapphire and Emerald, LeafGreen, Diamond, SoulSilver, and Black/White. I know I'm probably missing six Pearl exclusives, but is there anything else?

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I'm almost certain that you should be able to get every Pokemon, as long as they aren't event exclusive.

2 Answers

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If you're willing to hard reset on some of the games (to get different starters), then you can obtain every Pokemon except event exclusives, Glameow, Purugly, Palkia, Zorua, and Zoroark.
source

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–1 vote

Well, I can't think of any Pokemon you wouldn't be able to get that are either event Pokemon or exclusive Pokemon from Pokemon Black and Pokemon White.

But this list of Pokemon availability can help give you a quick run-through to tell you what Pokemon you might be missing. To me, it just seems like Palkia won't be available as you already know - and possibly even some starters if you don't want to trade.

Hope this helps! :)

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edited by
You contradicted your own source lol.
Alright