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In the anime and from the Ash-Hat Pikachu events, Ash's Pikachu's ability is Static.

Source: Knowledge of the Pokémon anime and Ash-Hat Pikachu events.

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As you say, the anime utilises his ability a lot.
Yes, one of the best episodes, you can see they talking about his ability is in the fight beetween pikachu and garbodor against Roxie, Gym battle.
True that, Olli.
Its ability is Static, and there are several references in the anime where an opposing Pokémon has become paralysed due to this ability. However, there are other times where Pikachu is able to absorb electric attacks that look suspiciously like Lightning Rod. And are we going to talk about Thunder Armour?