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So when I bring Ash Greninja over to Moon from the Demo, can I use a Synchronize Abra to get it Modest Nature? Or is it randomized? It will then be traded over to USUM but I don't think that affects it.

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Yes it is possible to use synchronise Abra on Ash greninja

Whether greninja is adamant, timid or modest, Greninja is still a gift Pokémon and can have his nature changed by Abra.

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