Fear not, your local Minccino expert has arrived.
HA Minccino is not obtainable in Black and White, only in Black and White 2 through the use of Hidden Grottoes, as Staka~ said.
For breeding in the later games, you can only obtain a HA Minccino through breeding if the parent already has that ability, and it has a 60% chance of being passed down regardless of gender. In addition, an Ability capsule will only switch between the Pokemon's two normal abilities.
I would recommend either DexNav chaining for one in ORAS (at certain Mirage spots) or SOS chaining for one in USUM (at Malie City's outer cape). If neither of these options are available to you, you will have to trade for one.
Source: Experience, and this.