PokéBase - Pokémon Q&A
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I know they include the first starter, but breeding them should be fair game.
I’m pretty sure the mascot legends are also locked.
Breeding them is fair game.

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This answer ignores events, as you can get some shinies like the Galarian birds through now-defunct gifts.

Base game

  • Every Pokemon above the current capture level
  • Grookey, Scorbunny, and Sobble when selecting a starter at the beginning of the game
  • The Charmander gift in Postwick
  • The Gigantamax Pikachu and Gigantamax Eevee gift in Meetup Spot
  • The Type: Null gift in the Battle Tower
  • The Toxel gift on Route 5
  • Zacian, Zamazenta, and Eternatus from the Energy Plant

Isle of Armor

  • Bulbasaur and Squirtle in the Master Dojo
  • Kubfu in the Master Dojo
  • Porygon in the Master Dojo
  • Meowth-Alola, Slowpoke, Vulpix-Alola, Sandshrew-Alola, Raichu-Alola, Marowak-Alola, Exeggutor-Alola, Diglett-Alola, Rowlet, Litten, and Popplio from the Diglett Man in the Fields of Honor

Crown Tundra

  • The Cosmog gift in Freezington
  • The Poipole gift in the Max Lair
  • Keldeo at Ballimere Lake
  • Articuno-Galar, Zapdos-Galar, and Moltres-Galar when roaming
  • Glastrier, Spectrier, and Calyrex at the Crown Shrine

Shiny Locked Pokemon (Serebii)

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All the shiny locked Pokemon in Sword and Shield are as follows:

  • Your starter, though if you breed it, its offspring can be shiny
  • The Charmander you get in Postwick
  • The Gigantamax Pikachu and Eevee you get from having data from the Let's Go Games
  • The Type: Null you get from the Battle Tower
  • The Gift Toxel you get on Route 5
  • The Box Legendaries
  • Eternatus

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