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In gen 3 the catagory a move is in is defined by its type i.e grass was special and poison was physical. Pokemon like sharpedo had a higher physical attack stat but could not use stab with it as both dark and water were special. Only gen 1-3 as that was before physical special split

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Gengar.
Flareon

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The following are the Pokemon that had a higher attack stat that couldn't use STAB with it:

  • Caterpie
  • Metapod
    Butterfree
    Pikachu
    Clefairy
    Clefable
    Wigglytuff
    Venomoth
    Ponyta
    Rapidash
    Slowpoke
    Shellder
    Cloyster
    Gastly
    Haunter
    Gengar
    Drowzee
    Krabby
    Kingler
    Lickitung
    Chansey
    Goldeen
    Seaking
    Gyarados
    Flareon
    Porygon
    Dratini
    Dragonair
    Totodile
    Croconaw
    Feraligathr
    Hoothoot
    Noctowl
    Ledyba
    Ledian
    Pichu
    Cleffa
    Igglybuff
    Togepi
    Togetic
    Azumarill
    Yanma
    Umbreon
    Misdreavus
    Sneasel
    Porygon2
    Magby
    Entei
    Mudkip
    Poocheyna
    Mightyena
  • Wurmple
  • Silcoon
    Beautifly
  • Cascoon
    Seedot
    Nuzleaf
    Shiftry
    Masqerain
    Illumise
    Carvanha
    Sharpedo
    Corphish
    Crawdaunt
    Feebas
    Absol
    Huntail
    Bagon
    Shelgon
  • Beldum

(Please note: A Pokemon's name with a bullet point aside it means that the Pokemon can get STAB from the stat, but can't learn any STAB moves)

Hope this helps!

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I think you missed some, like Magikarp and Mudkip.
Thanks. Also, Magikarp's base Special Attack is higher than it's base attack