PokéBase - Pokémon Q&A
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Meaning evolution only Pokemon, and breeding Pokemon, as well as Pokemon that are only obtained in gifts.

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Aren’t the gen 1 starters found in the friend safari?
And the Gen 6 Starters, so middle forms are fine I think, but not first forms of the Kanto or Kalos Starters.
https://bulbapedia.bulbagarden.net/wiki/Breloom_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Swalot_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Jumpluff_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Chandelure_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Dragapult_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Palossand_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Grapploct_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Polteageist_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Goodra_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Machamp_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Dusknoir_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Runerigus_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Alcremie_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Gourgeist_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Vivillon_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Raichu_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Omastar_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Omanyte_(Pok%C3%A9mon)#Game_locations
https://bulbapedia.bulbagarden.net/wiki/Lurantis_(Pok%C3%A9mon)#Game_locations
Pretty sure it's been established before that this site's location guide is pretty out of date. Might wanna go back and check stuff on Bulbapedia.
Wait… I need to check that I interpreted the question correctly.

You mean the Pokémon that can’t be caught in any game, right? And not a separate list for every game?
In any game please.

1 Answer

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Best answer

All Pokemon that are obtainable in Gen III can be caught in Pal Park. The contents of this answer ignore that.
Venusaur, Blastoise, Alolan Ninetales, Golem, Alolan Golem, Galarian Slowbro, Alolan Muk, Bayleef, Meganium, Quilava, Typhlosion, Croconaw, Feraligatr, Ampharos, Galarian Slowking, Treecko, Torchic, Mudkip, Jirachi, Turtwig, Torterra, Chimchar, Infernape, Piplup, Empoleon, Staraptor, Cranidos, Rampardos, Shieldon, Bastiodon, Wormadam, Mothim, Porygon-Z, Probopass, Phione, Manaphy, Snivy, Servine, Tepig, Pignite, Oshawott, Dewott, Simisear, Simisage, Simipour, Archeops, Meloetta, Chespin, Quiladdin, Fennekin, Braixen, Froakie, Frogadier, Florges, Diance, Hoopa, Volcanion, Rowlet, Dartrix, Decidueye, Litten, Torracat, Incineroar, Popplio, Brionne, Primarina, Crabominable, Lycanroc-Dusk, Type: Null, Silvally, Cosmog, Cosmoem, Magearna, Marshadow, Poipole, Naganadel, Zeraora, Meltan, Melmetal, Grookey, Thwackey, Rillaboom, Scorbunny, Raboot, Cinderace, Sobble, Drizzile, Inteleon, Dracozolt, Artcozolt, Dracovish, Arctovish, Kubfu, Urshifu, and Zarude.
Mew, Celebi, Darkrai, Shaymin, and Victini all require events that are no longer available to be caught. Arceus can be caught through use of an unreleased event.

Source: Cross-referencing the previous answer with Bulbapedia

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Thanks HT!