PokéBase - Pokémon Q&A
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Both types have their share of fast and slow pokemon, just like every type.

electric-Raichu, voltorb, electrode, electabuzz, jolteon, zapdos, raikou and manetric. All of these have a base speed over 100.

Psychic-Deoxys, mewtwo, alakazam, starmie, azelf, espeon, lugia, latias, latios, kadabra, mew, celebi, and jirachi. also have a base speed over 100.

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