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For national Dex type of format, does galarian slowbro work?Galarian slowbro has the ability quick draw, and can hold the quick claw. Combine the ability and item and 1/2 of the time slowbro will have priority to negate its abysmal 30 speed. The only flaw is that it only works 1/2 of the time. If you do think this strat will work what other Pokémon will synergize well with this? ( I’m trying a team centralizing on this in a few days.)

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Which meta are you talking about? OU, VGC, something else?
I'm going to assume you are taking about generation 9 National Dex. Galarian Slowbro is currently not ranked on the Smogon viability rankings, so I don't think its viable there.
Source: https://www.smogon.com/forums/threads/national-dex-viability-rankings.3714511/
As an aside, I remember that there were a lot of funny gimmick teams involving Belly Drum Galarian Slowbro with Quick Draw + Quick Claw in OU back when 8 was the current gen, but they were very inconsistent and never saw any high-level success. If you want to build around QD QC Slowbro,  consider using a Belly Drum set.
There is also a funny gimmick in National Dex where you can use defensive G. Slowbro with Regenerator and once certain Pokemon are taken out, you can mega evolve it into Mega slowbro which changes its typing and calm mind up and win

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Slowbro-Galar is tiered as being in National Dex RU by Smogon's usage-based tiering for National Dex and is NOT ranked in the viability rankings for National Dex. It also does NOT have a Smogon analysis for National Dex. It also is not mentioned in any remotely recent posts in the Viability Rankings or Metagame discussion threads.
In conclusion, Slowbro-Galar does NOT have much of a niche in National Dex currently and isn't very good in that format.
Note: The Smogon page linked below shows Slowbro-Galar as being in PU, but that is for regular competitive play, not National Dex.
EDIT: According to a user on Smogon forums, the reason Slowbro-Galar is not used is because it is outclassed by both Kantonian Slowbro (which can check physical water types like Urshifu-RS and Barraskewda as well as physical ground types thanks to its better bulk and typing) and Slowking-Galar (which can check special attacking fairy-types and has the same defensive typing).
Source: https://www.smogon.com/forums/threads/national-dex-viability-rankings.3714511/
https://www.smogon.com/dex/sv/pokemon/slowbro-galar/national-dex-ru/
https://www.smogon.com/forums/threads/national-dex-metagame-discussion.3710848/page-56#post-10167972

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Can you explain why it's unviable? Like what checks or outclasses it?
I asked in the PS! National Dex chatroom and I was told that it was not used mainly because it was outclassed by Galarian Slowking. I've also asked this on smogon forums and will update this answer with information on why it not used much once my question there gets answered.