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They both learn Trick Room. They have the same type.
Necrozma D-W has a lower Speed, making it better in Trick Room, and higher Def, SpD and SpA. Its ability decreases super effective hits' damage no matter what is HP is at.
Lunala's only advantages are a slightly higher HP, knowing a Ghost type attack, in Moongeist Beam, and access to an ability that decreases damage a little more, but for only the first hit.

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Don't play VGC, but maybe Shadow Shield? I honestly don't know, now I'm curious.
"an ability that decreases damage a little more, but only for the first hit" I think you underestimate how good Shadow Shield is.
Necrozma needs to get hit by 3 super effective moves before prism armor becomes better than shadow shield. In fast paced metagames like 4v4 doubles, this usually doesn't happen.
Either way, you'll probably get a better answer if you ask here: https://www.smogon.com/forums/threads/vgc-ask-a-simple-question-get-a-simple-answer.3588172/

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