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Is it possible to get the shiny starters (from Gens 1 through 4), Lucario, Manaphy, and Phione in anything but a Pokeball in DPPt/HGSS.

Hatching from eggs, cherish balls, transfers from other games work too.

Much thanks.

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You can catch a Riolu in a safari ball in HGSS.
Ayo thanks, this is the type of elite ball info I need.
Manaphy can be obtained in a Cherish Ball in DPPt with the DNS Exploit. Phione can be obtained in a Cherish Ball in My Pokemon Ranch when you trade Hayley a Leafeon after 250 Pokemon are deposited. My Pokemon Ranch can no longer be downloaded from the Wii Shop, so you will need to either cheat or have a Wii with the game preloaded.

The DNS Exploit can also apparently get you a Cherish Ball Charmander and Chimchar with a Japanese copy of Diamond or Pearl.
I should add that these need to be both shiny and legal in game, since I intend on getting these and using them in Scarlet/Violet, or Pokemon Champions.

However, discontinued software is not a problem and still “usable”.

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