PokéBase - Pokémon Q&A
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And where woud I find it?


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First off, the highest amount of EVs any pokemon can give is 3.
Pokemon that give off 3 atk EVs: Emboar, Stoutland, Gigalith, Conkeldurr, Leavanny, Krookodile, Eelektross, Haxorus, Terrakion, Tornadus, Thundurus, Zekrom.
Only Stoutland, Leavanny, Terrakion, Tornadus, Thundurus, Zekrom can be found wild
Stoutland : Route 10 / Cold storage shaking grass 5%
Leavanny: Route 6 / Lostlorn forest Shaking grass 5%
Rest: Encounter.

If you are talking about the highest atk stat, Zekrom First with max 438, Haxorus second with 432.

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Zekrom with base 150 has max 438
Then haxorous base 147 has max 432
Then concelduur archeops and darmantion have base 140atk With max 416
If your asking for evs spots rt1 patrat and lilipup give 1 Atk ev
Also in caves with gurdur2 boldore2(1def as well) drillbur1 and excadrill2
Forest area with levany 3
The highest evs that can be given by a Pokemon is 3 12with pokerus and macho brace
Pokemon in unova that give 3 (apparat from two levant and scoutland) Atk such as concelduur can't be found in the wild

edited by
swadloon gives 2 def EVs
O ye I get mixed up I ev train my deceive pokemon in pinwheel forest because there's whirlipeds thanks I'll edit that out ;)
who down voted this answer is perfectly fine