PokéBase - Pokémon Q&A
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which game?
thank you

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The are found throughout the game in various places on the ground, via Dowsing Machine or regular means. They can also be found in the Sinnoh Underground(Pearl, Diamond, and Platinum only), or bought at the Black City or White Forest Market(Black and White only).

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And if you don't win the pokemon world tournament in pokemon black and white 2 you are given a shard.