bwother and I are doing a combined answer, since it lets us be a little lazier and gets this thing answered c;
Sinnoh
Milotic (Cynthia) - Mirror Coat
Hippowdon (Bertha) - Curse
Golem (Roark, PWT) - Curse
Relicanth (Roark, PWT)- Amnesia
Medicham (Maylene, PWT) - Bullet Punch
Gastrodon (Crasher Wake, PWT) - Stockpile
Quagsire (Crasher Wake, PWT) - Curse
Drifblim (Fantina, PWT) - Tailwind (Only in Gen6)
Glaceon (Candice, PWT) - Yawn
Glalie (Candice, PWT) - Rollout
Unova
Simisage (Cilan, PWT) - Tickle
Simisear (Chili, PWT) - Low Kick
Camerupt (Chili, PWT) - Stockpile
Clefable (Lenora, PWT) - Wish
Escavalier (Burgh, PWT) - Megahorn
Accelgor (Burgh, PWT) - Spikes and Guard Split
Zebstrika (Elesa, PWT) - Me First
Galvantula (Elesa, PWT) - Disable
Stunfisk (Elesa, PWT) - Earth Power
Excadrill (Clay, PWT) - Submission
Seismitoad (Clay, PWT) - Earth Power
Unfezant (Skyla, PWT) - Hypnosis
Weavile (Bryce, PWT) - Ice Shard
Dewgong (Bryce, PWT) - Signal Beam, Stockpile
Walrein (Bryce, PWT) - Yawn
Druddigon (Drayden, PWT) - Fire Punch, Sucker Punch
Flygon (Drayden, PWT) - Earth Power
Salamence (Drayden, PWT) - Dragon Rush
Cinccino (Cheren, PWT) - Tail Whip
Lopunny (Cheren, PWT) - Ice Punch
Scolipede (Roxie, PWT) - Toxic Spikes
Garbordor (Roxie, PWT) - Rock Blast
Crobat (Roxie, PWT) - Brave Bird
Drapion (Roxie, PWT) - Night Slash
Jellicent (Marlon, PWT) - Recover, Acid Armor
Alomomola (Marlon, PWT) - Mirror Coat
Mantine (Marlon, PWT) - Signal Beam, Hydro Pump
Wailord (Marlon, PWT) - Aqua Ring
Toxicroak (Binaca, PWT) - Fake Out, Bullet Punch
Abomasnow (Binaca, PWT) - Leech Seed
Conkeldurr (Alder, PWT) - Mach Punch
Kalos
Talonflame (Malva, Battle Chateau) - Tailwind (It can be obtained without and with breeding)
Clawitzer (Siebold, Battle Chateau) - Aqua Jet and Crabhammer (Can be obtained with and without breeding)
Noivern (Drasna, Battle Chateau) - Tailwind