PokéBase - Pokémon Q&A
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I know it is in Mauvile Hills but where in Mauvile Hills? That place is huge.

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Yeah it's a bit tricky to get. You have to go through some things to get it.

  1. Go to Mauville Hills via the elevator to the right of the Gym. The left one works too, the right one is just closer to where you need to go.
  2. Once you're out of the elevator, keep going down until you see a man with sunglasses. Talk to him. A small event will take place between him and a man inside an apartment.
  3. Leave the area by going into another apartment or leaving the place and going back into it.
  4. Talk to the man again (he'll be in the same location). He will give you the Lopunnite.
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  • Go to Mauville Hills 2F
  • Go straight down after you exit the elevator
  • Turn right
  • Go down again until you reach a door on the left side with a man in a black suit standing in front of it
  • Interact with the man, and he will go away after a scene
  • Enter and exit a room, and the man will be standing in front of the room again
  • Interact with him, and he will give you a Lopunnite