PokéBase - Pokémon Q&A
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On one of the harbours in Castelia City, someone asks you which of the elemental monkeys you were given as a gift. Choose 'Pansage' (whether you got that one or not) and they will give you a Leaf Stone.

You can also find them in dust clouds (rare spots) in the various caves, or by showing all the Deerling forms to the scientist on route 6.

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1 vote

Another place to find a leafstone is on route 6 there will be three pokeballs on the ground two of them are wild pokemon and one is a leafstone

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Http://www.serebii.net/blackwhite/items.shtml

Go down to "Evolutionary items on that page, find Leaf STone, and it shows you the Locations. The easiest is Buy it in Black City.

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