PokéBase - Pokémon Q&A
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Does the Synchronize ability control a caught Pokémon's nature and if so, how does it work?

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Effect

If the opponent causes a burn, paralysis, or poisoning of a Pokémon with Synchronize, the opponent receives the status condition too. Self-inflicted status conditions (for example through the use of an item) are not passed on.

Changes

In Generations 3-4, bad poison is only passed on as regular poison.

Outside of battle

If a Pokémon with Synchronize is the leading party Pokémon, there is a 50% chance of each wild Pokémon encountered having the same nature.

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This doesn't really answer the question.
The question asks how synchronize works, and the answer told how synchronize works. What else do you want the answer to have?
I feel it's right. Go ahead and edit it if you think you're so smart!
Oh, I think I misunderstood the question. I was interpreting the question as "Does Synchronize have the ability to change the nature of Pokemon that have already been caught?".
Thank you, Sep. :3