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I'm guessing the answer is no -- the Steel-Type will be able to be hit by Poison-Type moves, but it won't be able to get poisoned. I think the only way to do it is with the Corrosion Ability but I wanted to check to make sure.

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You can also do this by changing the steel Pokemon's type. When it switches out, it'll regain its steel type but remain poisoned.

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No, it didn't work on showdown. For some reason, I can't find my replay. Oh well.

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I figured as much. Well, thanks!
No problem.