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I want to use Tympole early game.

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Olli is right, but "Kyogre"?

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You can catch tympole on route 102. It appears as a hidden Pokemon after you defeat Groudon/Kyogre. Which like what Olli said, is when you get the National Dex.
In short: no.

Source: Pokemon Omega Ruby and Pokemon Alpha Sapphire: The official National Pokedex

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