PokéBase - Pokémon Q&A
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I evolved my Nidorino into Nidoking at level 23, but it didn’t get the move Thrash! I tried to level up but, nothing happened!

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I don't remember exactly, but i think there is a move relearner in one of the sev islands who can make him remember a move in trade of two tiny Mushrooms or one big Mushroom. But i may be wrong.
Yeah, there’s a relearner on Two Island who wants either two Tiny Mushrooms or one Big Mushroom. You can farm Mushrooms by using Thief on Paras (or catching them) in Mt. Moon, if you don’t have enough.

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In FRLG only, it learns thrash at level 22. Sorry, I guess.

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