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In Pokemon Pearl

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Weavile and Floatzel are two of the 'mons I can think of.
Cynthia's Garchomp is my childhood trauma so far.

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The best Pokemon not just against her Garchomp but her entire team as a whole is Gyarados. By sending out Gyarados against Spiritomb, you can setup three or four dragon dances and just one shot her entire team with waterfall and ice fang. The only exception is her Milotic which can't hurt you in return so it is feasible to simply spam waterfall against it

Finally, do not rely on water types having ice type coverage to deal with Garchomp. It will not die to a non stab ice type move especially weaker ones such as a Golduck or Tentacruel ice beam. This is of course, assuming that both Pokemon are of similar levels

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This is Pearl, so you can't get a Froslass until getting the National Pokédex and beating the E4.
If Garchomp will not die to a non-STAB ice move, why do you recommend ice fang Gyarados?
Also
Lvl 57 100 SpA Choice Specs Floatzel Ice Beam vs. Lvl 62 0 HP / 0 SpD Garchomp: 228-272 (101.3 - 120.8%) -- guaranteed OHKO
Is it? I'll have to edit that out then. Damn dp sucks

@sumwun dragon dance. I mentioned that by setting up dd against Spiritomb, it can brute force its way thru Cymthia
@sumwun Her Garchomp is level 66 in DP.
Thanks for help
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Octillery seems like a good option.

Ice Beam to take out Garchomp instantly.
Also takes out Roserade and Togekiss.
Flamethrower to take out Lucario.
Bullet Seed to take out Milotic. (Might not go down in one turn)
Surf / Toxic is your best option against Spiritomb, since it has no weakness in Gen 4. Additionally you could use Toxic to take it down with passive damage.

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Is this better than Gyarados or Floatzel?
I believe it is, because it can take down almost the entire team.
What level does it need to be to take down almost the entire team? How do you know Gyarados can't do it at the same level?