PokéBase - Pokémon Q&A
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I'm unsure of whether it'd work because, technically it's not an overworld encounter. I want to know whether it'd be better to chain the Nav or risk getting the shiny I don't want in the grass.

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There’s no reason for it not to, since the Shiny Charm works on any wild encounters.

1 Answer

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I guess so, it's just like a normal encounter.
Source: https://m.bulbapedia.bulbagarden.net/wiki/DexNav

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