PokéBase - Pokémon Q&A
2 votes
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New evolution only recently discovered. Looks to be dependent on moves used in battle, so I'm guessing I should be able to bring in a level 100 Primeape from HOME as soon as that's a thing we can do, and it can evolve?

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2 Answers

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Best answer

Yes, after using Rage Fist 20 times, you can evolve it using Rare Candy. Similar to Gen 8, any level 100 Pokémon can be evolve using it.

Source: https://bulbapedia.bulbagarden.net/wiki/Rare_Candy

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In Gen 8, it is possible to evolve level 100 Pokemon that require a level up to evolve by using a Rare Candy on them. It is likely this feature carries to Scarlet/Violet.
Prove it
6 votes

Actually, YES you can...
If any Pokemon is at level 100 and requires a level up to evolve, you can use a rare candy on it to trigger evolution

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you cant i tried
@Tyler2002H: Could you provide a source?
https://twitter.com/ran_num/status/1595990857190371328?s=20&t=SIKJNlYIfEjToAqtvW3NPQ

Source of rare candy being used to evole a level 100 Pokemon. This is the correct answer.