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Definition of signature: only 1 evolutionary line had it in the game it was released in.
E.g. Wimpod - Ability: Wimp Out
Golisopod - Move: First Impression
Ability: Emergency Exit
Zygarde - Abilities: Aura Break, Power Construct
Moves: Land's Wrath, Thousand Arrows, etc.

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Best answer

Moves
(evolved Pokemon can know any move from a pre-evolution, so I don't think I need to include every evolved Pokemon with a signature move)

Gen 1
Beedrill: twineedle
Rattata: hyper fang, super fang
Ekans: glare
Oddish: petal dance
Paras: spore
Kadabra: kinesis
Shellder: clamp
Gastly: night shade
Krabby: crabhammer
Exeggcute: barrage
Cubone: bone club, bonemerang
Hitmonlee: jump kick, rolling kick, high jump kick
Kangaskhan: dizzy punch
Goldeen: waterfall
Jynx: lovely kiss
Magikarp: splash
Porygon: conversion, sharpen

Gen 2
Arcanine: extreme speed
Machop: vital throw
Porygon: conversion 2
Spinarak: spider web
Espeon: morning sun
Heracross: megahorn
Smeargle: sketch
Tyrogue: mach punch
Hitmontop: triple kick
Miltank: milk drink
Lugia: aeroblast
Ho-oh: sacred fire

Gen 3
Staryu: camouflage
Pichu: volt tackle
Grovyle: leaf blade
Blaziken: blaze kick
Marshtomp: muddy water
Slakoth: slack off
Makuhita: arm thrust
Volbeat: tail glow
Cacnea: needle arm
Seviper: poison tail
Castform: weather ball
Latias: mist ball
Latios: luster purge
Jirachi: doom desire
Deoxys: psycho boost

Gen 4
Vespiquen: defend order, heal order, attack order
Chatot: chatter
Rhyperior: rock wrecker
Dialga: roar of time
Palkia: spacial rend
Heatran: magma storm
Regigigas: crush grip
Giratina: shadow force
Cresselia: lunar dance
Manaphy: heart swap
Darkrai: dark void
Shaymin: seed flare
Arceus: judgment

Gen 5
Mewtwo: psystrike
Victini: searing shot
Tepig: heat crash
Zorua: night daze
Sawsbuck: horn leech
Klink: shift gear, gear grind
Bouffalant: head charge
Volcarona: fiery dance
Cobalion, Terrakion, Virizion, Keldeo: sacred sword
Reshiram and white Kyurem: fusion flare
Reshiram: blue flare
Zekrom and black Kyurem: fusion bolt
Zekrom: bolt strike
Kyurem: glaciate, ice burn, freeze shock
Keldeo: secret sword
Meloetta: relic song
Genesect: techno blast

Gen 6
Kyogre: origin pulse
Groudon: precipice blades
Rayquaza: dragon ascent
Greninja: mat block
Vivillon: powder
Litleo: noble roar
Eternal Floette: light of ruin
Pancham: parting shot
Aegislash: king's shield
Aromatisse: aromatic mist
Inkay: topsy-turvy
Helioptile: electrify
Hawlucha: flying press
Klefki: fairy lock, crafty shield
Phantump: forest's curse
Pumpkaboo: trick-or-treat
Xerneas: geomancy
Yveltal: oblivion wing
Zygarde: land's wrath
Diancie: diamond storm
Hoopa: hyperspace hole, hyperspace fury
Volcanion: steam eruption

Gen 7
Alolan Marowak: shadow bone
Spinarak: toxic thread
Heatmor: fire lash
Zygarde: thousand arrows, thousand waves, core enforcer (thousand arrows and thousand waves were arguably introduced in gen 6 but nothing was able to learn them)
Decidueye: spirit shackle
Incineroar: darkest lariat
Primarina: sparkling aria
Toucannon: beak blast
Crabominable: ice hammer
Oricorio: revelation dance
Ribombee: pollen puff
Lycanroc: accelerock
Toxapex: baneful bunker
Lurantis: solar blade
Tsareena: trop kick
Comfey: floral healing
Oranguru: instruct
Sandygast: shore up
Pyukumuku: purify
Silvally: multi-attack
Turtonator: shell trap
Togedemaru: zing zap
Dhelmise: anchor shot
Kommo-o: clanging scales
Tapu Koko, Tapu Lele, Tapu Bulu, Tapu Fini: nature's madness
Solgaleo, dusk mane Necrozma: sunsteel strike
Lunala, dawn wings Necrozma: moongeist beam
Necrozma: prismatic laser, photon geyser
Magearna: fleur cannon
Marshadow: spectral thief
Blacephalon: mind blown
Zeroara: plasma fists
Melmetal: double iron bash

Gen 8
Galarian Slowbro: shell side arm
Hisuinian Electrode: chloroblast
Galarian Weezing: strange steam
Galarian Articuno: freezing glare
Galarian Zapdos: thunderous kick
Galarian Moltres: fiery wrath
Hisuinian Typhlosion: infernal parade
Galarian Slowking: eerie spell
Hisuinian Qwilfish: barb barrage
Stantler: psyshield bash
Uxie, Mesprit, Azelf: mystical power
Phione, Manaphy: take heart
Hisuinian Samurott: ceaseless edge
Hisuinian Lilligant: victory dance
Hisuinian Zorua: bitter malice
Galarian Stunfisk: snap trap
Hisuinian Braviary: esper wing
Tornadus: bleakwind storm
Thundurus: wildbolt storm
Landorus: sandsear storm
Hisuinian Avalugg: mountain gale
Hisuinian Decidueye: triple arrows
Kommo-o: clangorous soul
Rillaboom: drum beating
Cinderace: court change, pyro ball
Inteleon: snipe shot
Skwovet: stuff cheeks
Chewtle: jaw lock
Coalossal: tar shot
Flapple: grav apple
Appletun: apple acid
Toxtricity: overdrive
Grapploct: octolock
Polteageist: teatime
Hatterene: magic powder
Morgrem: false surrender
Grimmsnarl: spirit break
Obstagoon: obstruct
Sirfetch'd: meteor assault
Alcremie: decorate
Falinks: no retreat
Morpeko: aura wheel
Dragapult: dragon darts
Crowned Zacian: behemoth blade
Crowned Zamazenta: behemoth bash
Eternatus: dynamax cannon, eternabeam
Single Urshifu: wicked blow
Rapid Urshifu: surging strikes
Zarude: jungle healing
Regieleki: thunder cage
Regidrago: dragon energy
Calyrex: glacial lance, astral barrage
Kleavor: stone axe
Sneasler: dire claw
Enamorus: springtide storm

Gen 9
Primeape: rage fist
Tauros: raging bull
Slowking: chilly reception
Girafarig: twin beam
Dunsparce: hyper drill
Greninja: water shuriken
Bloodmoon Ursaluna: blood moon
Meowscarada: flower trick
Skeledirge: torch song
Quaquaval: aqua step
Spidops: silk trap
Pawmot: double shock
Tandemaus: population bomb
Naclstack: salt cure
Armarouge: armor cannon
Ceruledge: bitter blade
Grafaiai: doodle
Scovillain: spicy extract
Rabsca: speed swap
Espartha: lumina crash
Tinkaton: gigaton hammer
Wugtrio: triple dive
Palafin: jet punch
Varoom: spin out
Veluza: fillet away
Dondozo: order up
Kingambit: kowtow cleave
Iron Treads: steel roller
Baxcalibur: glaive rush
Gholdengo: make it rain
Wo-chien, Chien-pao, Ting-lu, Chi-yu: ruination
Koraidon: collision course
Miraidon: electro drift
Walking Wake: hydro steam
Iron Leaves: psyblade
Dipplin: syrup bomb
Sinistcha: matcha gotcha
Ogerpon: ivy cudgel
Archaludon: electro shot
Hydrapple: fickle beam
Gouging Fire: burning bulwark
Raging bolt: thunderclap
Iron Boulder: mighty cleave
Iron Crown: tachyon cutter
Terapagos: tera starstorm
Pecharunt: malignant chain
source

Abilities

Gen 3
Psyduck, Golduck: cloud nine
Grimer, Muk: stench
Marill, Azumarill, Azurill: huge power
Wobbuffet, Wynaut: shadow tag
Tyranitar: sand stream
Lotad, Lombre, Ludicolo: rain dish
Slakoth, Slaking: truant
Shedinja: wonder guard
Meditite, Medicham: pure power
Plusle: plus
Minun: minus
Carvanha, Sharpedo: rough skin
Torkoal: white smoke
Milotic: marvel scale
Castform: forecast
Kecleon: color change
Kyogre: drizzle
Groudon: drought
Rayquaza: air lock

Gen 4
Clefairy, Clefable, Cleffa: magic guard
Machop, Machoke, Machamp: no guard
Shellder, Cloyster: skill link
Hitmonlee: reckless
Hitmonchan: iron fist
Mr. Mime, Mime Jr.: filter
Porygon, Porgon2, Porygon-Z: download
Shroomish, Breloom: poison heal
Skitty, Delcatty: normalize
Sableye: stall
Bidoof, Bibarel: unaware
Combee: honey gather
Cherrim: flower gift
Drifloon, Drifblim: unburden
Buneary, Lopunny: klutz
Bronzor, Bronzong: heatproof
Snover, Abomasnow: snow warning
Electivire: motor drive
Regigigas: slow start
Darkrai: bad dreams
Arceus: multitype

Gen 5
Ditto: imposter
Zangoose: toxic boost
Drifloon, Drifblim: flare boost
Victini: victory star
Darmanitan: zen mode
Yamask, Cofagrigus: mummy
Archen, Archeops: defeatist
Zorua, Zoroark: illusion
Ferroseed, Ferrothorn: iron barbs
Reshiram, white Kyurem: turboblaze
Zekrom, black Kyurem: teravolt

Gen 6
Mega Kangaskhan: parental bond
Primal Kyogre: primordial sea
Primal Groudon: desolate land
Mega Rayquaza: delta stream
Chespin, Quilladin, Chesnaught: bulletproof
Fletchling, Fletchinder, Talonflame: gale wings
Flabebe, Floette, Florges: flower veil, symbiosis
Skiddo, Gogoat: grass pelt
Furfrou: fur coat
Aegislash: stance change
Spritzee, Aromatisse: aroma veil
Swirlix, Slurpuff: sweet veil
Goomy, Sliggoo, Goodra: gooey
Xerneas: fairy aura
Yveltal: dark aura
Zygarde: aura break

Gen 7
Alolan Raichu: surge surfer
Alolan Diglett, Alolan Dugtrio: tangling hair
Alolan Geodude: galvanize
Alolan Grimer, Alolan Muk: power of alchemy
Greninja: battle bond
Zygarde: power construct
Rowlet, Dartrix, Decidueye: long reach
Popplio, Brionee, Primarina: liquid voice
Yungoos, Gumshoos: stakeout
Charjabug: battery
Oricorio: dancer
Wishiwashi: schooling
Mareanie, Toxapex: merciless
Mudbray, Mudsdale: stamina
Dewpider, Araquanid: water bubble
Salandit, Salazzle: corrosion
Stufful, Bewear: fluffy
Tsareena: queenly majesty
Comfey: triage
Passimian: receiver
Wimpod: wimp out
Golisopod: emergency exit
Sandygast, Palossand: water compaction
Pyukumuku: innards out
Silvally: RKS system
Minior: shields down
Komala: comatose
Mimikyu: disguise
Bruxish: dazzling
Drampa: berserk
Dhelmise: steelworker
Tapu Koko: electric surge
Tapu Lele: psychic surge
Tapu Bulu: grassy surge
Tapu Fini: misty surge
Solgaleo: full metal body
Lunala: shadow shield
Necrozma: prism armor, neuroforce
Magearna: soul-heart

Gen 8
Galarian Ponyta, Galarian Rapidash: pastel veil
Galarian Slowbro: quick draw
Galarian Slowking: curious medicine
Koffing, Weezing: neutralizing gas
Galarian Mr. Mime, Mr. Rime: screen cleaner
Galarian Darmanitan: gorilla tactics
Galarian Yamask, Runerigus: wandering spirit
Galarian Stunfisk: mimicry
Scorbunny, Raboot, Cinderace: libero
Corviknight: mirror armor
Gossifleur, Eldegoss: cotton down
Yamper: ball fetch
Rolycoly, Carkoal, Coalossal: steam engine
Applin, Flapple, Appletun: ripen
Silicobra, Sandaconda: sand spit
Cramorant: gulp missile
Arrokuda, Barraskewda: propeller tail
Toxtricity: punk rock
Perrserker: steely spirit
Cursola: perish body
Snom, Frosmoth: ice scales
Stonjourner: power spot
Eiscue: ice face
Morpeko: hunger switch
Duraludon: stalwart
Zacian: intrepid sword
Zamazenta: dauntless shield
Urshifu: unseen fist
Regieleki: transistor
Regidrago: dragon's maw
Glastrier: chilling neigh
Spectrier: grim neigh
Calyrex: as one

Gen 9
Bloodmoon Ursaluna: mind's eye
Male Oinkologne: lingering aroma
Dachsbun: well-baked body
Arbolivia: seed sower
Nacli, Naclstack, Garganacl: purifying salt
Bellibolt: electromorphosis
Wattrel, Kilowattrel: wind power
Toedscool, Toedscruel: mycelium might
Klawf: anger shell
Espartha: opportunist
Bombirdier: rocky payload
Palafin: zero to hero
Orthworm: earth eater
Glimmet, Glimmora: toxic debris
Flamigo: costar
Tatsugiri: commander
Farigiraf: armor tail
Kingambit: supreme overlord
Frigibax, Arctibax, Baxcalibur: thermal exchange
Gholdengo: good as gold
Wo-chien: tablets of ruin
Chien-pao: sword of ruin
Ting-lu: vessel of ruin
Chi-yu: beads of ruin
Koraidon: orichalcum pulse
Miraidon: hadron engine
Dipplin, Hydrapple: supersweet syrup
Poltchageist, Sinistcha: hospitality
Ogerpon: embody aspect
Terapagos: tera shift, tera shell, teraform zero
Pecharunt: poison puppeteer
source

by
edited ago by
thank's some one
I spent like an hour transcribing stuff that was already available on Bulbapedia. I hope OP is happy.
I am, thx
But why did you ask the question if the answer was already there?
Just reread the answer, and it says Smoliv's signature move is Terrain Pulse, and Raging Bolt's is Rising Voltage, even though they're Tutor Moves from the Isle of Armour,  Rabsca has Speed Swap which has also existed since before it was released, and Archaludon's is Electro Shock, which doesn't exist.
Spiky Shield, Water Shuriken, and Mystical Fire are also not on here, and there may be more that I didn't think of that are missed.
Next, (and these are very nitpicky), it says Battle Bond was introduced in Gen 6, when I'm pretty sure Ash-Greninja was released in Gen 7, and Calyrex has As One and Astral Barrage and Glacial Lance, but it only gets that when it fuses, so it should have the suffix of -Shadow Rider or -Ice Rider. Galarian Slowking should have Chilly Reception in Gen 8 also.
Finally, Tera Shell, Anger Shell, and Thunderous Kick are misspelled.

I'm sorry I'm complaining about your hard work, and if I had more points, I would edit it myself instead.

@sumwun, some people use this as their primary Pokemon source before going to other sites, or don't even know others exist,  so I felt that it would be benificial to them to have it here as well as other places.
Other Pokemon besides Rabsca became unable to learn speed swap in gen 9.
Spiky shield can be learned by Maractus or Glimmora in every generation where it existed, so it's not Chesnaught's signature move.
Another Pokemon can learn mystical fire in every generation where it existed, so it's not Delphox's signature move.
Chilly reception didn't exist in gen 8.