PokéBase - Pokémon Q&A
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The challengers cave is what I beleive you are referring to, and if you are, then there is really nothing in there but lots of higher level (50-60) Pokemon and trainers, making it an excellent place to train your Pokemon after you beat the elite four, as they will be too strong to rematch.

you can also get riolu, and tm voltswitch
TM volt switch is obtained by beating elesa, but yes you can find riolu in there
stone edge... it was obviously a spelling mistake
Also you can catch Rilou there!