PokéBase - Pokémon Q&A
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The challengers cave is what I beleive you are referring to, and if you are, then there is really nothing in there but lots of higher level (50-60) Pokemon and trainers, making it an excellent place to train your Pokemon after you beat the elite four, as they will be too strong to rematch.

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you can also get riolu, and tm voltswitch
TM volt switch is obtained by beating elesa, but yes you can find riolu in there
stone edge... it was obviously a spelling mistake
Also you can catch Rilou there!