Meta Rate My Team PokéBase - Pokémon Q&A
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You can go the Relic Passage, explore there because there is a secret doorway that leads to a deeper part of Relic Castle which can can't access in desert resort. From there you can catch Volcarona by interaction. There is no Volcarona on Route 3.

Source: Experience

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That's not Route 3.
I fixed it. Make sure you answer the question directly.
Yup.I That's where I caught my Volcarona.
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