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Says it all in the name

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If your intent is to use Toxic then repeatedly alternate between Detect and Protect, you should know that the strategy will not work. Consecutive uses of protection moves will increase the chance that they will fail, even if they are different moves entirely. If you would like to use a Toxic stall set, you're far better off using just Protect and leaving it at that.
oh cause i remember a team plasma memeber did that to me once and it never failed
If so then the spamming [email protected] got some A-class luck

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Yes!

The Pokémon that can learn all three of those moves are Cubone, Marowak, Hitmonchan, Eevee & the Eeveelutions, Zapdos, Yanma, Hitmontop, the Treecko, Grovyle, Sceptile, Makuhita, Hariyama, Sableye, Meditite, Medicham, Zangoose, Absol, Starly, Staravia, Staraptor, Riolu, Lucario, Yanmega, Azelf, Oshawott, Dewott, Samurott, Patrat, Watchog, Pidove, Tranquill, Unfezant, Timburr, Gurdurr, Conkeldurr, Scraggy, Scrafty, Zorua, Zoroark, Mienfoo, Mienshao and Hawlucha.

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