PokéBase - Pokémon Q&A
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I want to know because I want to evolve my Pikachu to a Raichu, but before I do I want to know if I need to switch out Pikanium Z for Electrium Z.


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Nah, Pikanium Z is only usable on Pikachu:

This item can be used on Pikachu in order to turn its Volt Tackle move into the Catastropika Z-Move

Hope I helped. :)

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thank you so much!
Also there is a special Z crystal for raichu. It makes thunderbolt stoked sparksurfer. It's in seafolk village (Steelix Sub) Talk to her but you need aloalan raichu in your party.