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Which one would hold more benefits for Pikachu in-game?

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Electrium-Z depends on what move you use it on, but Pikanium-Z only works on Volt Tackle. Electrium-Z might benefit Pikachu more since you can use it on any electric move, while Pikanium can be used only on Volt Tackle. You could use Pikanium-Z because it is its own Z-Move.

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okay, thank you!