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Rash increases Special Attack and lowers Special Defense.

Milotic's base stats are:

HP: 95
Attack: 60
Defense: 79
Special Attack: 100
Special Defense: 125
Spee: 81

As you can see, Milotic's best stat is it's Special Defense. Therefore having a nature which reduces this is not the best nature. The best possible nature for Milotic would be either Modest (+Special Attack, - Attack) or Calm (+ Special Defense, - Attack)