PokéBase - Pokémon Q&A
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Ice Punch in a move tutor move so you need to give 10 red shards to the guy in Driftveil City. Move tutor details.

You can also breed a female Azumarill/Marill with a compatible male Pokemon knowing Ice Punch. Any from Water 1 or Fairy would be compatible.

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You learn it from the move tutor in Driftveil City. You need 10 red shards.

Source: http://Pokemondb.net/pokedex/azumarill

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