Based on the responses on the internet and my own experience - since I have the shiny charm, it is highly unlikely, or even impossible to encounter a horde with all 5 being shiny.
Sweet scent just lures Pokemon faster and increases the encounters of hordes, but your chances still stay the same whether you use sweet scent of not. But, it might help since your increasing the probability of finding at least 1 shiny - not 5.
Hope I helped! :)