PokéBase - Pokémon Q&A
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This is for competitive battling, right? What format?

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Why though?
Sure, Sucker Punch only hits if the opponent is about to attack. But why waste a turn on it?

If you KO, it would have been better to just attack on the first turn. It's a waste of a turn.

If you didn't faint him after sucker punch, the priority didn't matter.

Overall, it would work, but is kinda pointless.