Learns Follow Me and Protect:
Learns Follow Me and Detect:
As we can see the Lucario family is the only one that gets all three moves. That being said having both of the Protect moves isn't recommended as they cant be used consecutively.
Also noteworthy is the move Rage Powder, which have the same effect as Follow Me, but very different Pokemon actually learn it.
As such, here are the Pokemon that learn Rage Powder and Protect (no Rage Powder user gets Detect):